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The gas state
Gases are probably the least familiar state to most people. Although
we stand on solid ground, we actually move through a gas; the air. We
breathe air, use it to pump up tyres, fly through it in planes and can
even be blown over by it. Our own bodies even produce gases but, because
we cannot see it, air and its component gases are not generally well understood.
We
can sense the presence of gas by smell if they have an odour, by feel
if they move, and by sight if they are colored. A still, odourless and
colorless gas, like nitrogen, oxygen or carbon dioxide, may as well not
exist in many people's minds.
Gases in the Universe
Next to the all powerful plasma state, gases are the next most common
state in the Universe. Gases are present in the vast gas nebula clouds
spread throughout space and in the giant gas planets like Jupiter and
Saturn. Most of the 1% of matter not in the stars as plasma is in the
gas state.
Gases on Earth
Most of the Earth's gas is found in its atmosphere. Natural gas accumulates
in pockets underneath the Earth's surface and some gas is dissolved in
the oceans and fresh water. By mass, gases are the third most common state
on Earth, behind liquids and solids.
What makes a gas different from solids and liquids?
Gases have no set volume, completely fill their container and take the
shape of that container. It does not matter how much or how little gas
is present, a gas will always fill its container.
If gases are not held in a container, dense heavy gases like carbon dioxide
will flow under the influence of gravity like a fluid. Light gases like
helium, on the other hand, will quickly escape from an open container
and mix or diffuse into surrounding gases.
Substances which are gases under normal conditions (25°C and 1 atmosphere
pressure) are usually made of light atoms or molecules weakly bonded together.
The particles in a gas vibrate, spin and move about with great speed.
Gas particles have enough motion to move about within their container,
bouncing off the walls of the container and each other.
In a normal gas, each particle has 1000 times its own space to move in
all directions. If gas particles were the same size as a marble with a
diameter of 1cm, there would be, on average, 10m to the next marble in
all directions. Gases under normal atmospheric pressure are 99.9% nothing
and 0.1% particles.
Measuring gases
With solids, the best way of measuring how much you have of a substance
is by weighing it and getting its mass. For liquids, volume is commonly
used. We buy butter by the kilogram and petrol by the litre, but what
about measuring the quantity of a gas? Since gases always fill their container,
volume is not enough. A pressure and temperature are required to specify
the quantity of a gas.
What is wrong with weighing a gas? Nothing, if you weigh them in a sealed
container with the weighing machine in a vacuum! Try to weigh a balloon
full of helium gas, it would rather float away than sit on a scale. The
problem is we are sitting in an ocean of invisible gas and air. Other
gases will float in air like a rubber duck floats on water.
Pressure, temperature and volume
By measuring the volume, temperature and pressure of a gas we can truly
state how much gas is present. If any one of the three properties changes,
the other two will also change. If a gas is kept in a container with a
set volume, such as a steel gas bottle, then, is heated, the pressure
will also rise, hence the danger of exploding gas bottles in a fire.
Similarly, if the temperature of a gas is kept constant, the volume will
change if the pressure on the gas changes. Helium balloons expand as they
rise though the air because the pressure on the outside of the balloon
gets less. The relationship between pressure and volume is called an inverse
relationship. As pressure decrease, volume increases and visa versa.
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